{"id":66,"date":"2017-05-05T06:59:52","date_gmt":"2017-05-05T06:59:52","guid":{"rendered":"http:\/\/www.shalomeo.com\/blog\/?p=66"},"modified":"2017-05-05T06:59:52","modified_gmt":"2017-05-05T06:59:52","slug":"design-and-synthesis-of-cdwo4-crystals","status":"publish","type":"post","link":"https:\/\/www.shalomeo.com\/blog\/design-and-synthesis-of-cdwo4-crystals\/66.html","title":{"rendered":"Design and Synthesis of cdwo4 crystals"},"content":{"rendered":"<p>Sb3+-activated <span style=\"color: #ff6600;\"><a style=\"color: #ff6600;\" href=\"http:\/\/www.shalomeo.com\/\"><strong>cdwo4 crystals<\/strong><\/a><\/span> phosphors were designed according to sp energy levels regularities of Sb3+ ion in some inorganic compounds. The sp energy levels regularities of Sb3+ in dozens of compounds were established with the aid of the dielectric theory of the chemical bond for complex crystals: EA = 6.2187\u22121.7584he, EB = 7.019\u22121.957he, EC = 7.259\u22121.964he.<\/p>\n<p>Environmental factor he of Cd site was calculated to be 1.6583 with the refined crystal structure and refractive index of cdwo4 crystals:Sb3+. Sb3+-doped cdwo4 crystals was synthesized through a precipitation method and its structure was refined with the General Structure Analysis System. The transition energy of A band of Sb3+ in cdwo4 crystals can be predicted to be 3.312 eV (374 nm), according to the relationship equation between EA and environmental factor he.<\/p>\n<p>By monitoring the 521 nm emission band, the excitation spectrum gives a weak excitation band peaking at 355 nm, which was assigned to the 1S0\u20133P1 transition of Sb3+ according to our prediction. Thus, Sb3+-doped cdwo4 crystals phosphor was designed and synthesized successfully based on sp energy levels regularities of Sb3+ ion. This work is a great help to understand the spectroscopy of Sb3+ ion and will be useful for the design and development of Sb3+-doped phosphors for applications.<\/p>\n<p style=\"color: #ff0000;\">This article comes from onlinelibrary edit released<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Sb3+-activated cdwo4 crystals phosphors were desig &hellip;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[2],"tags":[17],"_links":{"self":[{"href":"https:\/\/www.shalomeo.com\/blog\/wp-json\/wp\/v2\/posts\/66"}],"collection":[{"href":"https:\/\/www.shalomeo.com\/blog\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.shalomeo.com\/blog\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.shalomeo.com\/blog\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.shalomeo.com\/blog\/wp-json\/wp\/v2\/comments?post=66"}],"version-history":[{"count":0,"href":"https:\/\/www.shalomeo.com\/blog\/wp-json\/wp\/v2\/posts\/66\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.shalomeo.com\/blog\/wp-json\/wp\/v2\/media?parent=66"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.shalomeo.com\/blog\/wp-json\/wp\/v2\/categories?post=66"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.shalomeo.com\/blog\/wp-json\/wp\/v2\/tags?post=66"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}