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CLBO Crystals

  • Wide optical response wavelength range (UV absorption edge down to 180nm)
  • Processed and polished in low humidity environment, available as ingots, blanks, polished, and coated
  • Larger spectral and temperature acceptance, increased angular tolerance compared to bbo crystal
  • The nonlinear coefficient deff is almost twice that of the KDP crystal
  • Moderate birefringence and small walk-off angle
  • Large sizes available, fast deliveries
  • High efficiencies maintained for high power input
  • Ideal for: FHOG and FIHG for Nd: lasers, SHG and THG for Ti:Sapphire and Alexandrite lasers, UV laser optics, micro-photolithography
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Specifications:

Width Tolerance±0.1mmHeight Tolerance±0.1mm
Length Tolerance+0.5mm/-0.1mm (L≥2.5mm)
+0.1mm/-0.1mm (L<2.5mm)
Clear Aperture (Central of Diameter)90%
Surface Flatness (@633nm)≤lambda/6Parallelism20”
Surface Quality (MIL-PRF-13830B)10/5 S/DDamage Threshold>150 MW/cm^2 @266nm, 10ns, 10Hz (With AR Coating)
>300 MW/cm^2 @532nm, 10ns, 10Hz (With AR Coating)
Perpendicularity≦15’Angle ToleranceΔθ≦0.25°, ΔФ≦0.25 °
Chamfer≦0.2 mm × 45 °Chip≦0.1 mm


Basic Properties:

Chemical and Structural Properties
Chemical FormulaCsLiB6O10Crystal StructureTetragonal, Space group Ⅰ 42m
Lattice Constantsa = b = 10.494 Å, c = 8.939 ÅSymmetryz=4
Melting PointAround 844.5°Density2.461 g/cm3
Molecular Mass364.706
Optical and Nonlinear Optical Properties
Transmission Wavelength Range180-2750nmWalk-off Angle1.78 °at 1064nm;
1.83 °at 532nm;
0.98 °at 488nm
Effective NLO Coefficients1.01 pm/V at 532nm;
1.16 pm/V at 488nm;
0.95 pm/V at 1064nm
NLO Coefficientsdeff (Ⅰ) = d36 sinθmsin(2 Ф) ;
deff (Ⅱ) = d36 sin(2θm) sin(2 Ф)
Angle Acceptance1.02 mrad·cm at 1064 nm;
0.49 mrad·cm at 532 nm;
0.84 mrad·cm at 488 nm
Temperature Acceptance9.4℃·cm
Spectral Acceptance7.03 nm·cm at 1064 nm;
0.13 nm·cm at 532 nm;
0.09 nm·cm at 488 nm
Sellmeier Equations (λ in μm)CLBO at 20 ℃
no2 = 2.2104 + 0.01018 / (λ2 - 0.01424) - 0.01258 λ2
ne2 = 2.0588 + 0.00838 / (λ2 - 0.01363) - 0.00607 λ2
(0.1914 µm<λ<2.09 µm)

Cesium Lithium Borate (CLBO), chemical composition CsLiB6O10, is a nonlinear optical crystal highly valued in ultraviolet (UV) and deep-ultraviolet (DUV) applications because of its exceptional optical properties. CLBO offers a wide transmission wavelength range from approximately 180 nm to 2,300 nm, making them ideal for generating UV and DUV lasers. CLBO crystals have a relatively high nonlinear optical coefficient, which enables them to efficiently convert the frequencies of infrared lasers into shorter UV wavelengths through second, third, fourth, and even fifth harmonic generation. Additionally, CLBO exhibits a very high laser damage threshold, allowing it to withstand the high intensities often required in UV laser systems without suffering from optical damage. The crystal also features broad temperature and angular acceptance bandwidths, meaning it is easier to align and remains more stable under varying operating conditions compared to many other nonlinear crystals.

One of the major reasons CLBO is preferred as UV optics is its excellent performance in generating deep-UV light. It can produce wavelengths as short as 180–210 nm, which is particularly important for applications such as semiconductor photolithography, deep-UV spectroscopy, and high-resolution biomedical imaging. Compared to other nonlinear crystals like Beta Barium Borate (BBO), CLBO offers higher optical transmission below 200 nm and a lower walk-off angle, helping to maintain better beam quality during nonlinear frequency conversion processes. 

Hangzhou Shalom EO is a professional supplier of custom CLBO crystals for UV applications, offering crystal ingots, blanks, and polished or coated crystals tailored to diverse application requirements. CLBO crystals are available in a wide range of custom specifications, with options for various dimensions, orientations, and protective treatments. Given the highly hygroscopic nature of CLBO, Shalom EO treats every crystal with particular caution throughout the manufacturing and packaging processes. Leveraging decades of technical experience, the company has developed a unique technique for processing and polishing CLBO crystals under minimized humidity conditions, preventing deliquescence and preserving the optical quality of the material. This cutting-edge production method, which precisely controls environmental moisture levels, ensures that the crystals retain their integrity throughout manufacturing.

Thanks to this specialized know-how in precision polishing and moisture-controlled processing, Shalom EO delivers CLBO crystals with tight geometric control, high surface quality, and excellent performance. The crystals can also be supplied with anti-reflection (AR) coatings, protective coatings, or mounted in sealed housings to further enhance their durability and usability in demanding environments. Shalom EO’s cesium lithium borate (CLBO) crystals are recognized for their precise control over critical parameters and for achieving maximized conversion efficiencies, excelling as a nonlinear UV material for high-power lasers such as 193 nm excimer lasers and advanced UV optical systems.